Geopolymers from recycling materials
Valorization of industrial waste and industrial by-products
Principal investigators: Valentina Medri, Elena Landi, Annalisa Natali Murri
Involved personnel: Elettra Papa, Francesco Miccio, Cesare Melandri
Geopolymers are eco-sustainable materials because in addition to the low consolidation temperature, secondary raw materials can be used for their production. Depending on the final application of the product, ISTEC recycles as raw materials, inert or partially inert fillers, waste and industrial by-products of various kinds, some of which are examples.
- Powders and granules:
– Ashes from waste-to-energy processes (fly ash, bottom ash, biomass ash) are used as alkali-silicate raw material. Mixed biomass ashes (vegetal-animal) also contain hydroxyapatite (calcium phosphate) are partially reactive. Biomass ashes have been used to produce porous insulators such as sandwich panel cores with skins of fibrous reinforced basalt fiber in the POR-FESR EEE-CFCC project.
– Silica fume is a by-product of the industrial production of electric silicon metal and ferro-silicon alloys. The metal silicon present as impurity can be used as a blowing agent to produce foams by direct foaming.
– Porcelain stoneware scraps come from cutting and scrap production: they can be used as granules and sand as raw material because they are partially reactive in alkaline solution due to their glassy phase.
– Sheep wool from industrial waste is used in staple and felt to produce thermo-structural and insulating composites. Of particular interest are the properties of keratin for the release of nutrients in the soil and for the maintenance of moisture: containers for the early germination and soil improvers in the granules for horticulture have been made.
– Basalt fibers and carbon fibers from exhausted tires are used as secondary reinforcement for thermostructural and thermal shocks resistant materials, such as refractory molds for the casting of complex forms for fiber-reinforced materials.
Tools and Processes
The geopolymerization process is a reaction between an aluminosilicatic powder and an aqueous solution of hydroxides or alkaline silicates which, based on cations (commonly Na+, K+, but also Li+, Cs+), affects the final mechanical and thermal properties. Phosphate based geopolymer materials are the acid-base products of bi- and tri-valent metal oxides with aqueous phosphates in aqueous solution. Synthesis temperatures are lower than 100 ° C for “alkaline” and less than 300 ° C for phosphates. Mechanical mixing is required to complete the reaction. ISTEC is equipped with shear mixer (Planetary Centrifugal Mixer “THINKY MIXER” ARE-500). Hand layup and vacuum bagging or vacuum infiltration processes are used for fiber-reinforced composites.
- Tecnologie dei Materiali Faenza (ENEA-TEMAF)
- Centro Interdipartimentale per la Ricerca Industriale di Meccanica Avanzata e Materiali (CIRI-MAM)
- CertiMaC Soc. Cons. a Resp. Limitata (CERTIMAC)
- Tampieri Energie srl
Publications and patents
- Utility Model Patent “Composite Panels” del 15/12/2014, MI2014U000387, E. Landi, V. Medri, A. Natali Murri.
- Natali Murri A, Medri V, Landi E, Production and thermo-mechanical characterization of wool-geopolymer composites, Journal of the American Ceramic Society (2017), 100 (2017) 2822–2831
- Papa E, Medri V, Kpogbemabou D, Morinière V, Laumonier J, Vaccari A, Rossignol S, Porosity and insulating properties of silica-fume based foams, Energy and Buildings 131 (2016) 223–232.
- Natali Murri A, Medri V, Piancastelli A, Vaccari A, Landi E, Production and characterization of geopolymer blocks based on hydroxyapatite rich biomass ashes, Ceramics International 41 (2015) 12811–12822